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Journal of Energy Chemistry, Volume 28 : 73-78(2019) https://doi.org/10.1016/j.jechem.2018.01.010

Highly efficient electrocatalysts derived from carbon black supported non-precious metal macrocycle catalysts for oxygen reduction reaction

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  • ReceivedDec 27, 2017
  • AcceptedJan 16, 2018
  • PublishedJan 31, 2018

Abstract


Acknowledgment

This work was supported by the National Key Research and Development Program of China (2017YFA0206500); The National Natural Science Foundation (NSF) of China (51502012, 21676020); Beijing Natural Science Foundation (2162032, 17L20060); Young Elite Scientists Sponsorship Program by CAST (2017QNRC001); The Start-Up Fund for Talent Introduction of Beijing University of Chemical Technology (BUCTRC201420; BUCTRC201714); Talent Cultivation of State Key Laboratory of Organic-Inorganic Composites; Distinguished Scientist Program at BUCT (buctylkxj02) and the ‘‘111" Project of China (B14004).


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  • Fig. 1

    Schematic diagram of the synthesis of FePC-NH2/HCB.

  • Fig. 2

    SEM images of (a) FePC-NH2-800 and (b) FePC-NH2/HCB-800, (c) TEM image of FePC-NH2/HCB-800, (d) HRTEM image of FePC-NH2/HCB-800.

  • Fig. 3

    (a) XRD patterns of FePC-NH2/HCB-800 and FePC-NH2-800, (b) Raman spectra of FePC-NH2/HCB-800 and FePC-NH2-800, (c) high-resolution XPS spectra of N 1s of FePC-NH2/HCB-800.

  • Fig. 4

    (a) Polarization curves for the ORR activity, (b) Tafel plot of FePC-NH2/HCB-800, FePC-NH2-800, HCB-800 and Pt/C at 5 mV s−1. (c) LSV curves of FePC-NH2/HCB-800 catalyst at different rotating speeds at a scan rate of 5 mV s−1. The corresponding K–L plots of FePC-NH2/HCB-800 catalyst at different electrode potentials (inset in Fig. 4c). (d) Electron transfer number, (e) H2O2 yield of FePC-NH2/HCB-800, FePC-NH2-800, HCB-800 and Pt/C measured by RRDE. (f) LSV curves of FePC-NH2/HCB-800 before and after 10,000 potential cycles, and corresponding Tafel plot of them (inset in Fig. 4f).

  • Fig. 5

    (a) HRTEM image of FePC-NH2/HCB-800 treated with 1 M HCl. (b) XRD patterns of FePC-NH2/HCB-800 before and after being treated with 1 M HCl. (c) LSV curves of FePC-NH2/HCB-800, treated with 1 M HCl or 10 mM added KSCN in electrolyte.

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