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SCIENCE CHINA Materials, Volume 64 , Issue 12 : 2926-2937(2021) https://doi.org/10.1007/s40843-021-1700-5

Bimetal-organic framework-derived carbon nanocubes with 3D hierarchical pores as highly efficient oxygen reduction reaction electrocatalysts for microbial fuel cells

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  • ReceivedMar 4, 2021
  • AcceptedMay 7, 2021
  • PublishedJul 5, 2021

Abstract


Funded by

the National Natural Science Foundation of China(51976143)

the National Key Research and Development Program of China(2018YFA0702001)

and Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory(XHD2020-002)


Acknowledgment

This work was supported by the National Natural Science Foundation of China (51976143), the National Key Research and Development Program of China (2018YFA0702001), and Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (XHD2020-002).


Interest statement

The authors declare that they have no conflict of interest.


Contributions statement

Tang H conceived the idea of the subject and supervised the progress of the research. Chen N performed the experiments with support from Meng Z, Wang R, Cai S, and Guo W. Chen N wrote the manuscript, and Tang H revised the manuscript. All authors contributed to the general discussion.


Author information

Neng Chen obtained his bachelor’s degree from Guangdong University of Petroleum and Chemical Technology in 2015. He obtained a master’s degree from China University of Petroleum, Beijing in 2018. And he has been a scientific research assistant at the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing at Wuhan University of Technology until now. His research interests focus on electrocatalysts, fuel cells and metal-air batteries.


Haolin Tang earned his PhD degree in materials science from Wuhan University of Technology in 2007. Then he worked as a research fellow at Nanyang Technological University for one year, and in 2011 he was appointed as a full professor of the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing at Wuhan University of Technology. His research interests include fuel cells, electrochemistry of nanomaterials, and self-assembly of nanocomposites.


Supplement

Supplementary information

Supporting data are available in the online version of the paper.


References

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  • Figure 1

    (a) Diagram showing the synthesis of the 3D hierarchically porous Co-N-C skeleton; (b) XRD patterns of Zn(100−x)Cox(MeIM)@SiO2 (x = 0, 5, 10, 20, 50, 100), Zn90Co10(MeIM), simulated ZIF-8 and ZIF-67; (c) XRD patterns of Mes-C-N-Zn(100−x)Cox (x = 0, 5, 10, 20, 50, 100) and Mic-C-N-Zn90Co10.

  • Figure 2

    Physical characterizations. SEM images: (a, b) Mic-Zn90Co10(MeIM) nanocubes, (c, d) Mic-C-N-Zn90Co10 nanocubes and (e, f) Mes-C-N-Zn90Co10 nanocubes. TEM images: (g) HRTEM and (h) TEM images of the Mes-C-N-Zn90Co10 nanocubes. (i) Elemental mapping of the Mes-C-N-Zn90Co10 nanocubes.

  • Figure 3

    (a) N2 adsorption/desorption isotherms and (b) corresponding pore size distributions of Mes-C-N-Zn(100−x)Cox and Mic-C-N-Zn90Co10.

  • Figure 4

    XPS survey spectra of the (a) full spectrum; (b) Zn 2p; (c) N 1s; and (d) Co 2p of the Mes-C-N-Zn100, Mes-C-N-Zn90Co10, and Mes-C-N-Co100 catalysts.

  • Figure 5

    LSV curves of Mes-C-N-Co100, Mic-C-N-Zn90Co10, and commercial Pt/C at 1600 r min−1 in O2-saturated (a) 0.01 mol L−1 PBS, (b) 0.1 mol L−1 HClO4, and (c) 0.1 mol L−1 KOH. (d) LSV curves of Mes-C-N-Zn(100−x)Cox at 1600 r min−1 in 0.01 mol L−1 PBS. Methanol resistance curves of Pt/C and Mes-C-N-Zn90Co10 in (e) 0.1 mol L−1 HClO4 and (f) 0.1 mol L−1 KOH. Durability curves of Pt/C and Mes-C-N-Zn90Co10 in (g) 0.01 mol L−1 PBS, (h) 0.1 mol L−1 HClO4, and (i) 0.1 mol L−1 KOH.

  • Figure 6

    (a) Diagram showing the working principle of MFCs. (b) Polarization curves and discharge power densities of the 3D CoNC-MFC and Pt/C–MFC devices. (c) Voltage trend recorded for 192 h for the MFCs equipped with Mes-C-N-Zn90Co10 and Pt/C. The voltage was recorded across a 1000-Ω resistor.

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