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SCIENCE CHINA Materials, Volume 64 , Issue 12 : 2938-2948(2021) https://doi.org/10.1007/s40843-021-1689-4

In-situ electropolymerized bipolar organic cathode for stable and high-rate lithium-ion batteries

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  • ReceivedJan 21, 2021
  • AcceptedApr 21, 2021
  • PublishedJun 25, 2021

Abstract


Funding

the National Natural Science Foundation of China(51672188,52073211)


Acknowledgment

This work was supported by the National Natural Science Foundation of China (51672188 and 52073211).


Interest statement

The authors declare that they have no conflict of interest.


Contributions statement

Wang W conceived the ideas and performed the experiments and characterizations. Zhao C, Xiong P and Su H provided support for experimental feasibility. Xu Y supervised the project. Wang W wrote the paper; Yang J and Xu Y revised the paper. All authors contributed to the interpretation of the results and approved the final manuscript.


Author information

Wei Wang received her BSc degree from the Northeastern University in 2018. She is now a postgraduate under the supervision of Prof. Yunhua Xu at the School of Materials Science and Engineering, Tianjin University. Her current research mainly focuses on the synthesis and characterization of organic cathode materials for electrochemical energy storage devices.


Yunhua Xu is a professor at the School of Materials Science and Engineering, Tianjin University. He received PhD degree in materials physics and chemistry from the South China University of Technology in 2008. Prior to joining Tianjin University, he worked as a visiting student and postdoc at the University of California, Santa Barbara, Iowa State University and the University of Maryland, College Park, from 2006 to 2015. His research interests focus on electrochemical storage materials and devices.


Supplementary data

Supplementary information

Supporting data are available in the online version of the paper.


References

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  • Figure 1

    (a) Molecular structure, (b) HOMO and LUMO energy levels, and (c) n-type and p-type reactions of APCNDI.

  • Figure 2

    (a, c) Galvanostatic charge/discharge profiles of APCNDI cathode under different potential ranges at 1 A g−1, and (b, d) cycling performance of APCNDI cathode under different potential ranges of (a, b) 1.5–3.0 V and (c, d) 3.0–4.4 V at 1 A g−1. Schematic illustrations of the APCNDI cathode cycling in (e) 1.5–3.0 V, (f) 3.0–4.4 V, and (g) electrochemical polymerization reaction.

  • Figure 3

    (a) Digital images of PP separators and (b) electrolytes soaked with APCNDI electrodes after 500 cycles at 1 A g−1 under different voltage windows. (c) UV-vis spectra, (d) FTIR spectra, and (e) SEM images of pristine and cycled APCNDI cathodes in different voltage ranges of 1.5–3.0 and 1.5–4.4 V. (f) Reaction of in-situ electropolymerization.

  • Figure 4

    Electrochemical performance of APCNDI cathodes: (a) CV curves at 0.05 mV s−1, (b) selected charge/discharge profiles, (c) cycling performance in the voltage range from 1.5–4.4 V at 0.1 A  g−1, (d) rate performance, and (e) long-term cycling performance at 5 A g−1.

  • Figure 5

    (a) Galvanostatic charge/discharge profiles with marked points for FTIR and XPS tests. (b) FTIR spectra and (c) high-resolution N 1s and O 1s spectra of APCNDI cathode at different charge/discharge states marked in (a). (d) Mechanism illustration of the n- and p-type reactions of APCNDI.

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