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Tunable nonlinear optical responses based on host-guest MOF hybrid materials

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  • ReceivedJun 17, 2020
  • AcceptedJul 5, 2020
  • PublishedOct 14, 2020

Abstract


Funding

the National Natural Science Foundation of China(51632008,U1609219,61721005)


Acknowledgment

This work was supported by the National Natural Science Foundation of China (51632008, U1609219 and 61721005).


Interest statement

The authors declare that they have no conflict of interest.


Contributions statement

Li H and Zhang L designed and performed the experiments, analyzed the data and wrote the paper; He H, Yang Y and Cui Y analyzed the data; Qian G conceived the framework of this paper and revised the paper. All authors contributed to the general discussion.


Author information

Hongjun Li received his Bachelor’s degree in materials science and engineering from Northeastern University (2017). He is currently pursuing a PhD at the School of Materials Science and Engineering at Zhejiang University under the supervision of Prof. Guodong Qian. His research interest focuses on photonic MOF materials.


Guodong Qian received his Bachelor’s (1988) and Master’s (1992) degrees in materials science from Zhejiang University. He was promoted to Associate Professor, Full Professor, and Cheung Kong Professor in 1999, 2002, and 2011, respectively. His current research interests include hybrid organic-inorganic photonic functional materials and multifunctional porous materials.


Supplementary data

Supplementary information

Supporting data are available in the online version of the paper.


References

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  • Figure 1

    (a) Schematic diagram of synthesizing ZJU-68 and LDS-722@ZJU-68 hybrid microcrystals. (b) The corresponding powder XRD patterns of ZJU-68 and dye-assembled ZJU-68 microcrystals.

  • Figure 2

    (a) TPL emission spectra of LDS-722 and LDS-722@ZJU-68 excited at 1020 nm. (b) SHG spectra of ZJU-68, KDP, and LDS-722@ZJU-68 crystals excited at 1020 nm.

  • Figure 3

    (a) The emission spectra which were analyzed under four different excitation polarizations (θ = 0°–90°), excited at 1200 nm. Inset: schematic diagram of the measurement geometry for an individual crystal. (b) TPL and (c) SHG intensity plotted against polarization direction of incident light in LDS-722@ZJU-68 at 1200 nm (5.22 mJ cm−2) from 0° to 360°. The red and blue lines indicate the cos2θ and cos4θ fits for TPL and SHG, respectively.

  • Figure 4

    (a) 800 nm pumped emission spectra of LDS-722@ZJU-68. Insets: the micrograph of LDS-722@ZJU-68 crystal excited at 800 nm (left) and log-log plots for the SHG intensity vs. the excitation energy density, showing a slope of ∼ 2.02 (right). (b) 1000 nm pumped emission spectra of LDS-722@ZJU-68. Insets: the micrograph of LDS-722@ZJU-68 crystal excited at 1000 nm (left) and log-log plots for the SHG and TPL intensities vs. the excitation energy densities, showing the slopes of ∼ 2.25 and 1.89, respectively (right). (c) 1200 nm pumped emission spectra of LDS-722@ZJU-68. Insets: the micrograph of LDS-722@ZJU-68 crystal excited at 1200 nm (left) and log-log plots for the SHG intensity vs. the excitation energy density, showing the slope of ∼ 1.92 (top right) and two-photon emission intensity as a function of pump energy showing the lasing threshold at ∼7.74 mJ cm−2 and the FWHM showing a dramatical decrease from ∼ 67 to ∼ 0.9 nm (bottom right). (d) 1400 nm pumped emission spectra of LDS-722@ZJU-68. Insets: the micrograph of LDS-722@ZJU-68 crystal excited at 1400 nm (left) and log-log plots for the SHG and THG intensities vs. the excitation energy densities with the slopes of ∼ 1.94 and 2.90, respectively (right). Scale bars: 15 μm.

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