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SnSe2 nanocrystals coupled with hierarchical porous carbon microspheres for long-life sodium ion battery anode

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  • ReceivedSep 11, 2019
  • AcceptedDec 4, 2019
  • PublishedDec 30, 2019

Abstract


Funded by

the National Key R&D Research Program of China(2016YFB0100201)

Beijing Natural Science Foundation(JQ18005)

the National Natural Science Foundation of China(51671003,21802003)

China Postdoctoral Science Foundation(2019TQ0001)

and the start-up supports from Peking University and Young Thousand Talented Program.


Acknowledgment

This work was supported by the National Key R&D Research Program of China (2016YFB0100201), Beijing Natural Science Foundation (JQ18005), the National Natural Science Foundation of China (51671003, 21802003), China Postdoctoral Science Foundation (2019TQ0001), and the start-up supports from Peking University and Young Thousand Talented Program.


Interest statement

The authors declare no conflict of interest.


Contributions statement

Guo S conceived the project and directed the experiment. Chen H designed the experiments. Chen H, Mu Z and Li Y prepared and carried out the main experiments and characterization. Chen H wrote the manuscript. All authors contributed to the data analysis, discussed the results, and commented on the manuscript.


Author information

Hui Chen is a PhD student of the University of Electronic Science and Technology of China under the supervision of Prof. Jinshu Wang. Currently, he is studying at Peking University as an exchange student in Prof. Shaojun Guo’s group. His research interests include the synthesis and characterization of nanomaterials for alkali-ion batteries, photocatalysis and perovskite solar cells.


Shaojun Guo received his BSc degree in Jilin University (2005) and PhD degree in the Chinese Academy of Sciences (2010). He worked as a postdoctoral researcher associate at Brown University (2011–2013) and as a prestigious Oppenheimer Distinguished Fellow at Los Alamos National Laboratory (2013–2015). He joined the College of Engineering, Peking University in 2015 and is currently a Professor. His research interests focus on engineering nanocrystals and 2D materials for catalysis, renewable energy, optoelectronics and biosensors.


Supplement

Supplementary information

Experimental details and supporting data are available in the online version of the paper.


References

[1] Dunn B, Kamath H, Tarascon JM. Electrical energy storage for the grid: A battery of choices. Science, 2011, 334: 928-935 CrossRef PubMed Google Scholar

[2] Shen L, Yu Y. Greener and cheaper. Nat Energy, 2017, 2: 836-837 CrossRef Google Scholar

[3] Larcher D, Tarascon JM. Towards greener and more sustainable batteries for electrical energy storage. Nat Chem, 2015, 7: 19-29 CrossRef PubMed Google Scholar

[4] Luo W, Shen F, Bommier C, et al. Na-ion battery anodes: Materials and electrochemistry. Acc Chem Res, 2016, 49: 231-240 CrossRef PubMed Google Scholar

[5] Firouzi A, Qiao R, Motallebi S, et al. Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries. Nat Commun, 2018, 9: 861 CrossRef PubMed Google Scholar

[6] Xiang X, Zhang K, Chen J. Recent advances and prospects of cathode materials for sodium-ion batteries. Adv Mater, 2015, 27: 5343-5364 CrossRef PubMed Google Scholar

[7] Yu L, Wang LP, Liao H, et al. Understanding fundamentals and reaction mechanisms of electrode materials for Na-ion batteries. Small, 2018, 14: 1703338 CrossRef PubMed Google Scholar

[8] Li Z, Bommier C, Chong ZS, et al. Mechanism of Na-ion storage in hard carbon anodes revealed by heteroatom doping. Adv Energy Mater, 2017, 7: 1602894 CrossRef Google Scholar

[9] Park H, Kwon J, Choi H, et al. Microstructural control of new intercalation layered titanoniobates with large and reversible d-spacing for easy Na+ ion uptake. Sci Adv, 2017, 3: e1700509 CrossRef PubMed Google Scholar

[10] Wu T, Jing M, Yang L, et al. Controllable chain-length for covalent sulfur-carbon materials enabling stable and high-capacity sodium storage. Adv Energy Mater, 2019, 9: 1803478 CrossRef Google Scholar

[11] Fang Y, Liu Q, Xiao L, et al. A fully sodiated NaVOPO4 with layered structure for high-voltage and long-lifespan sodium-ion batteries. Chem, 2018, 4: 1167-1180 CrossRef Google Scholar

[12] Wang S, Xia L, Yu L, et al. Free-standing nitrogen-doped carbon nanofiber films: integrated electrodes for sodium-ion batteries with ultralong cycle life and superior rate capability. Adv Energy Mater, 2016, 6: 1502217 CrossRef Google Scholar

[13] Li Y, Mu L, Hu YS, et al. Pitch-derived amorphous carbon as high performance anode for sodium-ion batteries. Energy Storage Mater, 2016, 2: 139-145 CrossRef Google Scholar

[14] Pan H, Hu YS, Chen L. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage. Energy Environ Sci, 2013, 6: 2338 CrossRef Google Scholar

[15] Nie Z, Fava D, Kumacheva E, et al. Self-assembly of metal–polymer analogues of amphiphilic triblock copolymers. Nat Mater, 2007, 6: 609-614 CrossRef PubMed Google Scholar

[16] Ma D, Li Y, Mi H, et al. Robust SnO2−x nanoparticle-impregnated carbon nanofibers with outstanding electrochemical performance for advanced sodium-ion batteries. Angew Chem Int Ed, 2018, 57: 8901-8905 CrossRef PubMed Google Scholar

[17] Miao C, Liu M, He YB, et al. Monodispersed SnO2 nanospheres embedded in framework of graphene and porous carbon as anode for lithium ion batteries. Energy Storage Mater, 2016, 3: 98-105 CrossRef Google Scholar

[18] Zhao K, Zhang L, Xia R, et al. SnO2 quantum dots@graphene oxide as a high-rate and long-life anode material for lithium-ion batteries. Small, 2016, 12: 588-594 CrossRef PubMed Google Scholar

[19] Liang J, Yu XY, Zhou H, et al. Bowl-like SnO2@carbon hollow particles as an advanced anode material for lithium-ion batteries. Angew Chem Int Ed, 2014, 53: 12803-12807 CrossRef PubMed Google Scholar

[20] Xiong X, Yang C, Wang G, et al. SnS nanoparticles electrostatically anchored on three-dimensional N-doped graphene as an active and durable anode for sodium-ion batteries. Energy Environ Sci, 2017, 10: 1757-1763 CrossRef Google Scholar

[21] He P, Fang Y, Yu XY, et al. Hierarchical nanotubes constructed by carbon-coated ultrathin SnS nanosheets for fast capacitive sodium storage. Angew Chem Int Ed, 2017, 56: 12202-12205 CrossRef PubMed Google Scholar

[22] Liu Y, Yu XY, Fang Y, et al. Confining SnS2 ultrathin nanosheets in hollow carbon nanostructures for efficient capacitive sodium storage. Joule, 2018, 2: 725-735 CrossRef Google Scholar

[23] Luo B, Fang Y, Wang B, et al. Two dimensional graphene–SnS2 hybrids with superior rate capability for lithium ion storage. Energy Environ Sci, 2012, 5: 5226-5230 CrossRef Google Scholar

[24] Jiang Y, Wei M, Feng J, et al. Enhancing the cycling stability of Na-ion batteries by bonding SnS2 ultrafine nanocrystals on amino-functionalized graphene hybrid nanosheets. Energy Environ Sci, 2016, 9: 1430-1438 CrossRef Google Scholar

[25] Xu Y, Peng B, Mulder FM. A high-rate and ultrastable sodium ion anode based on a novel Sn4P3-P@graphene nanocomposite. Adv Energy Mater, 2018, 8: 1701847 CrossRef Google Scholar

[26] Li Q, Li Z, Zhang Z, et al. Low-temperature solution-based phosphorization reaction route to Sn4P3/reduced graphene oxide nanohybrids as anodes for sodium ion batteries. Adv Energy Mater, 2016, 6: 1600376 CrossRef Google Scholar

[27] Wang W, Li P, Zheng H, et al. Ultrathin layered snse nanoplates for low voltage, high-rate, and long-life alkali-ion batteries. Small, 2017, 13: 1702228 CrossRef PubMed Google Scholar

[28] Yuan S, Zhu YH, Li W, et al. Surfactant-free aqueous synthesis of pure single-crystalline SnSe nanosheet clusters as anode for high energy- and power-density sodium-ion batteries. Adv Mater, 2017, 29: 1602469 CrossRef PubMed Google Scholar

[29] Zhang F, Xia C, Zhu J, et al. SnSe2 2D anodes for advanced sodium ion batteries. Adv Energy Mater, 2016, 6: 1601188 CrossRef Google Scholar

[30] Choi J, Jin J, Jung IG, et al. SnSe2 nanoplate–graphene composites as anode materials for lithium ion batteries. Chem Commun, 2011, 47: 5241-5243 CrossRef PubMed Google Scholar

[31] Wei Z, Wang L, Zhuo M, et al. Layered tin sulfide and selenide anode materials for Li- and Na-ion batteries. J Mater Chem A, 2018, 6: 12185-12214 CrossRef Google Scholar

[32] Xiang Huang Z, Liu B, Kong D, et al. SnSe2 quantum dot/rGO composite as high performing lithium anode. Energy Storage Mater, 2018, 10: 92-101 CrossRef Google Scholar

[33] Sun W, Rui X, Yang D, et al. Two-dimensional tin disulfide nanosheets for enhanced sodium storage. ACS Nano, 2015, 9: 11371-11381 CrossRef Google Scholar

[34] Yao J, Liu B, Ozden S, et al. 3D nanostructured molybdenum diselenide/graphene foam as anodes for long-cycle life lithium-ion batteries. Electrochim Acta, 2015, 176: 103-111 CrossRef Google Scholar

[35] Qu B, Ma C, Ji G, et al. Layered SnS2-reduced graphene oxide composite-a high-capacity, high-rate, and long-cycle life sodium-ion battery anode material. Adv Mater, 2014, 26: 3854-3859 CrossRef PubMed Google Scholar

[36] Jiang X, Yang X, Zhu Y, et al. In situ assembly of graphene sheets-supported SnS2 nanoplates into 3D macroporous aerogels for high-performance lithium ion batteries. J Power Sources, 2013, 237: 178-186 CrossRef Google Scholar

[37] Ko YN, Choi SH, Park SB, et al. Hierarchical MoSe2 yolk–shell microspheres with superior Na-ion storage properties. Nanoscale, 2014, 6: 10511-10515 CrossRef PubMed Google Scholar

[38] Zhou X, Wan LJ, Guo YG. Binding SnO2 nanocrystals in nitrogen-doped graphene sheets as anode materials for lithium-ion batteries. Adv Mater, 2013, 25: 2152-2157 CrossRef PubMed Google Scholar

[39] Zhai C, Du N, Zhang H, et al. Multiwalled carbon nanotubes anchored with SnS2 nanosheets as high-performance anode materials of lithium-ion batteries. ACS Appl Mater Interfaces, 2011, 3: 4067-4074 CrossRef PubMed Google Scholar

[40] Yang C, Feng J, Lv F, et al. Metallic graphene-like VSe2 ultrathin nanosheets: superior potassium-ion storage and their working mechanism. Adv Mater, 2018, 30: 1800036 CrossRef PubMed Google Scholar

[41] Wang W, Jiang B, Qian C, et al. Pistachio-shuck-like MoSe2/C core/shell nanostructures for high-performance potassium-ion storage. Adv Mater, 2018, 30: 1801812 CrossRef PubMed Google Scholar

[42] Xiao Y, Su D, Wang X, et al. CuS microspheres with tunable interlayer space and micropore as a high-rate and long-life anode for sodium-ion batteries. Adv Energy Mater, 2018, 8: 1800930 CrossRef Google Scholar

[43] Fang G, Wang Q, Zhou J, et al. Metal organic framework-templated synthesis of bimetallic selenides with rich phase boundaries for sodium-ion storage and oxygen evolution reaction. ACS Nano, 2019, 13: 5635-5645 CrossRef Google Scholar

[44] Cai Y, Cao X, Luo Z, et al. Caging Na3V2(PO4)2F3 microcubes in cross-linked graphene enabling ultrafast sodium storage and long-term cycling. Adv Sci, 2018, 5: 1800680 CrossRef PubMed Google Scholar

[45] Feng Y, Chen S, Wang J, et al. Carbon foam with microporous structure for high performance symmetric potassium dual-ion capacitor. J Energy Chem, 2020, 43: 129-138 CrossRef Google Scholar

[46] Liu X, Zhao L, Wang S, et al. Hierarchical-structure anatase TiO2 with conductive network for high-rate and high-loading lithium-ion battery. Sci Bull, 2019, 64: 1148-1151 CrossRef Google Scholar

[47] Liu R, Liang Z, Gong Z, et al. Research progress in multielectron reactions in polyanionic materials for sodium-ion batteries. Small Methods, 2018, 3: 1800221 CrossRef Google Scholar

[48] Wang WA, Huang H, Wang B, et al. A new dual-ion battery based on amorphous carbon. Sci Bull, 2019, 64: 1634-1642 CrossRef Google Scholar

[49] Hao J, Peng S, Qin T, et al. Fabrication of hybrid Co3O4/NiCo2O4 nanosheets sandwiched by nanoneedles for high-performance supercapacitors using a novel electrochemical ion exchange. Sci China Mater, 2017, 60: 1168-1178 CrossRef Google Scholar

[50] Guo S, Sun Y, Liu P, et al. Cation-mixing stabilized layered oxide cathodes for sodium-ion batteries. Sci Bull, 2018, 63: 376-384 CrossRef Google Scholar

[51] Xu ZL, Park J, Yoon G, et al. Graphitic carbon materials for advanced sodium-ion batteries. Small Methods, 2018, 3: 1800227 CrossRef Google Scholar

[52] Jiang H, Zhao T, Ren Y, et al. Ab initio prediction and characterization of phosphorene-like SiS and SiSe as anode materials for sodium-ion batteries. Sci Bull, 2017, 62: 572-578 CrossRef Google Scholar

[53] Li M, Yang W, Huang Y, et al. Hierarchical mesoporous Co3O4@ZnCo2O4 hybrid nanowire arrays supported on Ni foam for high-performance asymmetric supercapacitors. Sci China Mater, 2018, 61: 1167-1176 CrossRef Google Scholar

  • Figure 1

    (a) Schematic illustration of the formation process of SnSe2 NCs/C microspheres. SEM images of the as-synthesized Sn-precursor microspheres (b, e); SnO2 NCs/C microspheres (c, f) and SnSe2 NCs/C microspheres (d, g).

  • Figure 2

    (a) Typical SEM image of SnSe2 NCs/C microspheres and the corresponding elemental mapping of (b) tin, selenium, and carbon elements. (c) TEM and (d) HRTEM images of SnSe2 NCs/C.

  • Figure 3

    (a) PXRD patterns of the as-synthesized Sn-precursor, SnO2 NCs/C, and SnSe2 NCs/C microspheres. (b) Nitrogen adsorption-desorption isotherms and pore size distribution (the inset) of SnSe2 NCs/C microspheres. XPS spectra of the SnSe2 NCs/C microspheres survey (c), C 1s (d), Sn 3d (e), and Se 3d (f).

  • Figure 4

    (a) CV curves of the SnSe2 NCs/C in the first five cycles at a scan rate of 0.1 mV s−1. (b) Charge-discharge profiles for the SnSe2 NCs/C at 100 mA g−1 in the first five cycles. (c) Cycling performances of the SnSe2 NCs/C and bulk SnSe2 at 100 mA g−1 for 100 cycles. (d) Rate performances of the SnSe2 NCs/C and bulk SnSe2 at various current densities from 0.1 to 1 A g−1. (e) CV curve with the pseudocapacitive contribution shown in the olive region at a scan rate of 5 mV s−1. (f) The bar chart shows the contribution ratios of capacitive capacity and diffusion-limited capacity at various scan rates. (g) Long-term cycle performance of SnSe2 NCs/C at 1 A g−1 for 1000 cycles.