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Organic solar cells based on chlorine functionalized benzo[1,2-b:4,5-b′]difuran-benzo[1,2-c:4,5-c′]dithiophene-4,8-dione copolymer with efficiency exceeding 13%

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  • ReceivedNov 27, 2019
  • AcceptedJan 10, 2020
  • PublishedMar 11, 2020

Abstract


Funded by

the National Natural Science Foundation of China(21674007,51825301,21975012,21875204,21875204,21734001)


Acknowledgment

This work was supported by the National Natural Science Foundation of China (21674007, 51825301, 21975012, 21875204, 21875204, 21734001). HYW is grateful for the financial support from the National Research Foundation (NRF) of Korea (NRF-2019R1A2C2085290, 2019R1A6A1A11044070).


Interest statement

The authors declare that they have no conflict of interest.


Supplement

The supporting information is available online at http://chem.scichina.com and http://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.


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  • Figure 1

    (a) Molecular structures of PBF1-C, PBF1-C-2Cl, and Y6. (b) Normalized absorption of PBF1-C, PBF1-C-2Cl, and Y6 films. Absorption of PBF1-C (c) and PBF1-C-2Cl (d) in chlorobenzene solutions at different temperature. (e) Energy level diagram of PBF1-C, PBF1-C-2Cl, and Y6 obtained from cyclic voltammetry measurements. 2D GIWAXS patterns for PBF1-C (f) and PBF1-C-2Cl (g) neat film (color online).

  • Figure 2

    (a) Current density-voltage (J-V) curves and (b) the corresponding EQE spectra of PBF1-C:Y6 and PBF1-C-2Cl:Y6 devices. (c) Jph versus Veff curves and (d) Jsc versus light intensity of PBF1-C:Y6 and PBF1-C-2Cl:Y6 devices (color online).

  • Figure 3

    AFM and TEM images of PBF1-C:Y6 (a–c) and PBF1-C-2Cl:Y6 (d–f) (color online).

  • Figure 4

    2D GIWAXS patterns for (a) PBF1-C:Y6 blend film, (b) PBF1-C-2Cl:Y6 blend film, and (c) the corresponding out-of-plane and in-plane line-cut profiles (the dashed line represents the in-plane direction, and the solid line shows the out-of-plane direction) (color online).

  • Table 1   Optical and electrochemical data of PBF1-C, PBF1-C-2Cl, and Y6

    λmax a) (nm)

    λmaxb) (nm)

    λonsetb) (nm)

    Egopt c) (eV)

    Eox (V)

    HOMO (eV)

    Ered (V)

    LUMO (eV)

    PBF1-C

    626

    633

    683

    1.82

    1.01

    −5.43

    −0.90

    −3.52

    PBF1-C-2Cl

    594

    635

    691

    1.79

    1.20

    −5.61

    −0.91

    −3.51

    Y6

    834

    946

    1.31

    1.36

    −5.77

    −0.31

    −4.11

    In dilute chloroform solution. b) In thin film drop cast from chloroform solution. c) Estimated from empirical formula: Egopt=1240/λonset.

  • Table 2   The photovoltaic parameters of OSCs with PBF1-C:Y6 and PBF1-C-2Cl:Y6 as active layers

    Active layer

    Voc (V)

    Jsc(mA cm−2)

    Jsc,cal(mA cm−2)

    FF (%)

    PCEa) (%)

    PBF1-C:Y6

    0.74

    (0.74±0.01)

    25.21

    (25.12±0.19)

    24.34

    66.0

    (65.9±0.3)

    12.31

    (12.22±0.08)

    PBF1-C-2Cl:Y6

    0.83

    (0.83±0.01)

    23.88

    (23.59±0.24)

    22.95

    66.0

    (66.2±0.9)

    13.10

    (12.91±0.21)

    The average values with standard deviations were obtained from ten devices and the maximum values are shown in parenthesis.

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