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SCIENCE CHINA Chemistry, Volume 61 , Issue 12 : 1619-1623(2018) https://doi.org/10.1007/s11426-018-9316-4

Chlorine-passivated superatom Al37 clusters for nonlinear optics

More info
  • ReceivedMay 7, 2018
  • AcceptedJun 21, 2018
  • PublishedSep 21, 2018

Abstract


Funded by

the Key Research Program of Frontier Sciences(QYZDB-SSW-SLH024)

the National Natural Science Foundation of China(21722308)

the National Thousand Youth Talents Program.


Acknowledgment

This work was supported by the Key Research Program of Frontier Sciences (QYZDB-SSW-SLH024), the National Natural Science Foundation of China (21722308) and the National Thousand Youth Talents Program.


Interest statement

The authors declare that they have no conflict of interest.


Supplement

The supporting information is available online at http://chem.scichina.com and http://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.


References

[1] Luo Z, Castleman AW. Acc Chem Res, 2014, 47: 2931-2940 CrossRef PubMed Google Scholar

[2] Reber AC, Khanna SN. Acc Chem Res, 2017, 50: 255-263 CrossRef PubMed Google Scholar

[3] Häkkinen H. Chem Soc Rev, 2008, 37: 1847-1859 CrossRef PubMed Google Scholar

[4] Clemenger K. Phys Rev B, 1985, 32: 1359-1362 CrossRef ADS Google Scholar

[5] Fedrigo S, Harbich W, Buttet J. Phys Rev B, 1993, 47: 10706-10715 CrossRef ADS Google Scholar

[6] de Heer WA, Selby K, Kresin V, Masui J, Vollmer M, Chatelain A, Knight WD. Phys Rev Lett, 1987, 59: 1805-1808 CrossRef PubMed ADS Google Scholar

[7] Knight WD, Clemenger K, de Heer WA, Saunders WA, Chou MY, Cohen ML. Phys Rev Lett, 1984, 52: 2141-2143 CrossRef ADS Google Scholar

[8] de Heer WA. Rev Mod Phys, 1993, 65: 611-676 CrossRef ADS Google Scholar

[9] Alexandrova AN, Boldyrev AI, Zhai HJ, Wang LS. Coord Chem Rev, 2006, 250: 2811-2866 CrossRef Google Scholar

[10] Li WL, Romanescu C, Jian T, Wang LS. J Am Chem Soc, 2012, 134: 13228-13231 CrossRef PubMed Google Scholar

[11] Luo Z, Castleman Jr. AW, Khanna SN. Chem Rev, 2016, 116: 14456-14492 CrossRef PubMed Google Scholar

[12] Leuchtner RE, Harms AC, Castleman Jr. AW. J Chem Phys, 1989, 91: 2753-2754 CrossRef ADS Google Scholar

[13] Cheng L, Yuan Y, Zhang X, Yang J. Angew Chem Int Ed, 2013, 52: 9035-9039 CrossRef PubMed Google Scholar

[14] Qian H, Zhu Y, Jin R. J Am Chem Soc, 2010, 132: 4583-4585 CrossRef PubMed Google Scholar

[15] Jadzinsky PD, Calero G, Ackerson CJ, Bushnell DA, Kornberg RD. Science, 2007, 318: 430-433 CrossRef PubMed ADS Google Scholar

[16] Whetten RL, Price RC. Science, 2007, 318: 407-408 CrossRef PubMed Google Scholar

[17] Zeng C, Chen Y, Kirschbaum K, Lambright KJ, Jin R. Science, 2016, 354: 1580-1584 CrossRef PubMed ADS Google Scholar

[18] Henke P, Trapp N, Anson CE, Schnöckel H. Angew Chem Int Ed, 2010, 49: 3146-3150 CrossRef PubMed Google Scholar

[19] Klinkhammer KW, Uhl W, Wagner J, Hiller W. Angew Chem Int Ed Engl, 1991, 30: 179-180 CrossRef Google Scholar

[20] Schnöckel H. Chem Rev, 2010, 110: 4125-4163 CrossRef PubMed Google Scholar

[21] Ecker A, Weckert E, Schnöckel H. Nature, 1997, 387: 379-381 CrossRef ADS Google Scholar

[22] Walter M, Akola J, Lopez-Acevedo O, Jadzinsky PD, Calero G, Ackerson CJ, Whetten RL, Grönbeck H, Häkkinen H. Proc Natl Acad Sci USA, 2008, 105: 9157-9162 CrossRef PubMed ADS Google Scholar

[23] Luo Z, Reber AC, Jia M, Blades WH, Khanna SN, Castleman AW. Chem Sci, 2016, 7: 3067-3074 CrossRef Google Scholar

[24] Yan Z, Bao R, Huang Y, Chrisey DB. J Phys Chem C, 2010, 114: 11370-11374 CrossRef Google Scholar

[25] Zeng H, Du XW, Singh SC, Kulinich SA, Yang S, He J, Cai W. Adv Funct Mater, 2012, 22: 1333-1353 CrossRef Google Scholar

[26] Scaramuzza S, Zerbetto M, Amendola V. J Phys Chem C, 2016, 120: 9453-9463 CrossRef Google Scholar

[27] Sheik-Bahae M, Said AA, van Stryland EW. Opt Lett, 1989, 14: 955-957 CrossRef ADS Google Scholar

[28] Wu H, Yuan C, Luo Z. J Mater Chem C, 2017, 5: 7561-7566 CrossRef Google Scholar

[29] Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Mennucci B, Petersson GA, Nakatsuji H, Caricato M, Li X, Hratchian HP, Izmaylov AF, Bloino J, Zheng G, Sonnenberg JL, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Vreven T, Montgomery JAJr, Peralta JE, Ogliaro F, Bearpark M, Heyd JJ, Brothers E, Kudin KN, Staroverov VN, Kobayashi R, Normand J, Raghavachari K, Rendell A, Burant JC, Iyengar SS, Tomasi J, Cossi M, Rega N, Millam JM, Klene M, Knox JE, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Martin RL, Morokuma K, Zakrzewski VG, Voth GA, Salvador P, Dannenberg JJ, Dapprich S, Daniels AD, Farkas O, Foresman JB, Ortiz JV, Cioslowski J, Fox DJ. Gaussian 09. Wallingford: Gaussian, Inc., 2009, 19: 227–238. Google Scholar

[30] Perdew JP, Burke K, Ernzerhof M. Phys Rev Lett, 1996, 77: 3865-3868 CrossRef PubMed ADS Google Scholar

[31] Adamo C, Barone V. J Chem Phys, 1999, 110: 6158-6170 CrossRef ADS Google Scholar

[32] Gonzalez C, Schlegel HB. J Chem Phys, 1989, 90: 2154-2161 CrossRef ADS Google Scholar

[33] Glendening ED, Landis CR, Weinhold F. WIREs Comput Mol Sci, 2012, 2: 1-42 CrossRef Google Scholar

[34] Podagatlapalli GK, Hamad S, Sreedhar S, Tewari SP, Venugopal Rao S. Chem Phys Lett, 2012, 530: 93-97 CrossRef ADS Google Scholar

[35] Luo YR. Handbook of Bond Dissociation Energies in Organic Compounds. Boca Raton: Taylor & Francis Group, LLC, 2002. Google Scholar

[36] Kuladeep R, Jyothi L, Prakash P, Mayank Shekhar S, Durga Prasad M, Narayana Rao D. J Appl Phys, 2013, 114: 243101 CrossRef ADS Google Scholar

[37] Jin R, Liu C, Zhao S, Das A, Xing H, Gayathri C, Xing Y, Rosi NL, Gil RR, Jin R. ACS Nano, 2015, 9: 8530-8536 CrossRef Google Scholar

[38] Aguado A, López JM. J Phys Chem Lett, 2013, 4: 2397-2403 CrossRef Google Scholar

[39] Abreu MB, Powell C, Reber AC, Khanna SN. J Am Chem Soc, 2012, 134: 20507-20512 CrossRef PubMed Google Scholar

[40] Castro-Lopez M, Brinks D, Sapienza R, van Hulst NF. Nano Lett, 2011, 11: 4674-4678 CrossRef PubMed ADS Google Scholar

  • Scheme 1

    (a) A sketch showing the homemade setup for laser ablation of aluminium (LAL) rod in liquid. (b) The customized experimental setup for Z-scan nonlinear optics measurements (color online).

  • Figure 1

    UV/Vis absorption spectra of the as-prepared aluminum clusters (a), with a comparison to that of the commercial Al powders dispersed in CH2Cl2 (b). The inset shows a photograph of the CH2Cl2 solvent, Al powder and the cluster sample (color online).

  • Figure 2

    Typical high-resolution electrospray ionization mass spectra (ESI-MS) of the aluminum clusters, in negative mode, with methanol as the mobile phase (color online).

  • Figure 3

    Millikan charge distribution, electrostatic potential, and frontier molecular orbitals of the neutral clusters Al37 (a) and Al37Cl6 (b) at the pbepbe/tzvp level of theory (color online).

  • Figure 4

    (A) Reaction coordinate for the formation of Al37Cl clusters at the pbepbe/tzvp level of theory. (B) NBO donor-acceptor interactions in Al37-Cl-CH2Cl complex of (a) initial adsorbed state I (b) transition state (TS) (c) desorption product (P). Pink, green, dark grey and light grey atoms refer to Al, Cl, C and H, respectively (color online).

  • Figure 5

    Normalized transmittance of aluminium chloride clusters (~1.17×10−4 mol  dm−3) plotted by Z-scan measurement under the conditions of open aperture (a), and closed aperture (b) conditions, along with the fitted curves (color online).

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