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SCIENCE CHINA Chemistry, Volume 64 , Issue 6 : 1004-1008(2021) https://doi.org/10.1007/s11426-021-9981-3

Isolation of a carbon nanohoop with Möbius topology

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  • ReceivedJan 4, 2021
  • AcceptedMar 15, 2021
  • PublishedApr 27, 2021

Abstract


Funded by

the National Science Foundation of China(21873079,21771155,92061103,21721001,21573179)

the Ministry of Science and Technology of China(2017YFA0204902)

the Fundamental Research Funds for the Central Universities(20720180035)

and the Top-Notch Young Talents Program of China.


Acknowledgment

This work was supported by the National Natural Science Foundation of China (21873079, 21771155, 92061103, 21721001, 21573179), the Ministry of Science and Technology of China (2017YFA0204902), the Fundamental Research Funds for the Central Universities (20720180035), and the Top-Notch Young Talents Program of China.


Interest statement

The authors declare no conflict of interest.


Contributions statement

These authors contributed equally to this work.


Supplement

The supporting information is available online at http://chem.scichina.com and http://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.


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  • Figure 1

    (a) Möbius-conjugated nanohoops 3m[12]CPP; (b) postulated nanoribbon with Möbius topology derived from the 3m[12]CPP (color online).

  • Figure 2

    Synthetic route of 3m[12]CPP (color online).

  • Figure 3

    Crystal structures of 3m[12]CPP. (a) ORTEP drawing (thermal ellipsoids shown at 30% probability) and space-filling model showing of 3m[12]CPP. (b) The Möbius strip derived from 3m[12]CPP. The meta-linked chain and para-linked chain are highlighted in orange and blue, respectively (color online).

  • Figure 4

    (a) Dissected EDDB results for 3m[12]CPP at the CAM-B3LYP/6-311G(d,p) level. (b) The ACID plots for 3m[12]CPP. Isovalues for EDDBπ, EDDBσ, and ACID isosurfaces are 0.015, 0.008, and 0.035 respectively (color online).

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